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1 article(s) from Davis, Rebecca

Biochemistry of fluoroprolines: the prospect of making fluorine a bioelement

Vladimir Kubyshkin,
Rebecca Davis and
Nediljko Budisa

Beilstein J. Org. Chem. 2021, 17, 439–460, doi:10.3762/bjoc.17.40

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Graphical Abstract

Figure 1: The structures of the fluoroprolines discussed herein.

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Figure 2: The distinction between “the alanine and the proline worlds”. While the polyalanine backbone leads ...

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Figure 3: Molecular volume for 20 coded amino acids and fluoroprolines. The COSMO volume was calculated for a...

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Figure 4: Comparative analysis of the electrostatic potential for proline and fluoroprolines (electrostatic p...

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Figure 5: Experimental logP data for methyl esters of N-acetylamino acids.

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Figure 6: The conformational dependence of the proline ring on the fluorination at position 4.

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Figure 7: Rotation around the peptidyl-prolyl fragments in polypeptide structures is important for correct ov...

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Figure 8: The complex fate of a protein-encoded amino acid in the cell (EF-Tu – elongation factor thermo unst...

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Figure 9: Metabolic routes for proline in E. coli. A) Synthesis of proline and B) degradation of proline.

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Figure 10: A complete flowchart for the proline incorporation into proteins during ribosomal biosynthesis. A) ...

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Figure 11: Amide bond formation capacities of fluoroprolines compared to some coded amino acids measured on ri...

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Figure 12: Ribbon representation of the X-ray crystal structures of proteins containing fluoroprolines. A) Enh...

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Figure 13: Problems and phenomena associated with the production of a protein-containing proline-to-fluoroprol...

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Figure 14: Effects of fluoroprolines on recombinant protein expression using the auxotrophic expression host E...

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Figure 15: A) Experimental setup for the incorporation of fluoroprolines into proteins. B) Adaptive laboratory...

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Review

Published 15 Feb 2021

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